If the molecule is not spherical then the relevant term is the harmonic mean of the rotational relaxation times (rh ) about the principle rotational axes
A plot of 1/P - 1/3 versus T/h predicts a straight line, the intercept and slope of which permit determination of Po and the molar volume (if the lifetime is known).   Shown below is such a plot (termed a Perrin-Weber plot) for protoporphyrin IX associated with apohorseradish peroxidase - the viscosity of the solvent is varied by addition of sucrose.
Polarization VII