As the degree of conjugation increases
(i.e the number of electrons involved in the
delocalized p-orbitals)
the absorption energy decreases (> l, the energy
between the ground and
excited state decreases)
the absorption becomes more intense (>e,
increased probability of absorption)
Benzene < Naphthalene
< Anthracene < naphthacene < pentacene
Abs. Max
262nm 275 nm 375 nm 475 nm 580 nm
Log e
3.84 3.75 3.90 4.05 4.20
(Extinction)